攻博期间的科学研究计划书

攻博期间的科学研究计划书
## Research Plan for Doctoral Studies.
Abstract.
Over the past few decades, there has been a growing interest in the development of new materials for use in various applications. One of the most promising classes of materials is metal-organic frameworks (MOFs), which are porous crystalline materials constructed from metal ions or clusters and organic linkers. MOFs have been shown to exhibit a wide range of properties, including high surface area, tunable pore size and shape, and high thermal and chemical stability. These properties make MOFs ideal candidates for a variety of applications, such as gas storage, separation, and catalysis.
In this research plan, I propose to investigate the synthesis and characterization of novel MOFs for use in gas storage and separation applications. I will use a variety
of synthetic techniques to prepare MOFs with different pore sizes and shapes, and I will characterize their structural and physical properties using a combination of techniques such as X-ray diffraction, gas sorption, and scanning electron microscopy. I will also investigate the performance of these MOFs in gas storage and separation applications, and I will optimize their properties for these applications.
The successful completion of this research project will lead to the development of new MOFs with improved properties for gas storage and separation applications. These MOFs could have a significant impact on the fields of energy and environmental science.
Research Goals.
The goal of this research project is to develop new MOFs with improved properties for gas storage and separation applications. Specifically, I will focus on the following research goals:
Synthesize novel MOFs with different pore sizes and shapes.
Characterize the structural and physical properties of these MOFs.
Investigate the performance of these MOFs in gas storage and separation applications.
Optimize the properties of these MOFs for gas storage and separation applications.
Research Methodology.
I will use a variety of synthetic techniques to prepare MOFs with different pore sizes and shapes. These techniques include solvothermal synthesis, hydrothermal synthesis, and mechanochemical synthesis. I will also use a variety of techniques to characterize the structural and physical properties of these MOFs, including X-ray diffraction, gas sorption, and scanning electron microscopy.
To investigate the performance of these MOFs in gas storage and separation applications, I will use a combination of experimental and computational methods. I will measure the gas sorption isotherms of these MOFs for a variety of gases, and I will use these data to calculate their gas storage capacities and selectivities. I will also use computational methods to simulate the gas sorption behavior of these MOFs, and I will use these simulations to gain a better understanding of the mechanisms of gas storage and separation in these materials.
Expected Outcomes.
The successful completion of this research project will lead to the development of new MOFs with improved properties for gas storage and separation applications. These MOFs could have a significant impact on the fields of energy and environmental science.
Specifically, the expected outcomes of this research project include:
The synthesis of novel MOFs with different pore sizes and shapes.
The characterization of the structural and physical properties of these MOFs.
The investigation of the performance of these MOFs in gas storage and separation applications.
The optimization of the properties of these MOFs for gas storage and separation applications.
## 攻博期间的科学研究计划。

摘要。

近几十年来，人们对新型材料在各种应用中的开发兴趣日益浓厚。

其中最有前途的一类材料是金属有机骨架（MOF），这是一种由金属离子或团簇和有机连接体构建的多孔晶体材料。

研究表明，MOF 具有广泛的性能，包括高表面积、可调控的孔径和形状以及高热稳定性和化学稳定性。

这些特性使得 MOF 成为各种应用（例如储气、分离和催化）的理想候选材料。

在本研究计划中，我提议研究新型 MOF 的合成和表征，以便将
其用于储气和分离应用。

我将使用各种合成技术制备具有不同孔径
和形状的 MOF，并将使用 X 射线衍射、气体吸附和扫描电子显微镜
等多种技术组合对它们的结构和物理特性进行表征。

我还会研究这
些 MOF 在储气和分离应用中的性能，并优化它们在这些应用中的特性。

本研究项目的成功完成将导致开发出具有改进性能的新型 MOF，用于储气和分离应用。

这些 MOF可能会对能源和环境科学领域产生
重大影响。

研究目标。

本研究项目的目标是开发出具有改进性能的新型 MOF，用于储
气和分离应用。

具体来说，我将重点关注以下研究目标：
合成具有不同孔径和形状的新型 MOF.
表征这些 MOF 的结构和物理性能。

研究这些 MOF在储气和分离应用中的性能。

优化这些 MOF 的特性，用于储气和分离应用。

研究方法。

我将使用各种合成技术来制备具有不同孔径和形状的 MOF。

这
些技术包括溶剂热合成、水热合成和机械化学合成。

我还将使用各
种技术对这些 MOF 的结构和物理性能进行表征，包括 X 射线衍射、气体吸附和扫描电子显微镜。

为了研究这些 MOF 在储气和分离应用中的性能，我将结合使用
实验和计算方法。

我将测量这些 MOF 对各种气体的吸附等温线，并
将使用这些数据计算它们的储气能力和选择性。

我还会使用计算方
法模拟这些 MOF 的气体吸附行为，并将使用这些模拟来更好地理解
这些材料中储气和分离的机制。

预期成果。

本研究项目的成功完成将导致开发出具有改进性能的新型 MOF，用于储气和分离应用。

这些 MOF可能会对能源和环境科学领域产生
重大影响。

具体来说，本研究项目的预期成果包括：
合成具有不同孔径和形状的新型 MOF.
表征这些 MOF 的结构和物理性能。

研究这些 MOF在储气和分离应用中的性能。

优化这些 MOF 的特性，用于储气和分离应用。