SIGMA-ALDRICH Material Safety Data SheetVersion 4.0Revision Date 03/13/2010Print Date 02/28/20111. PRODUCT AND COMPANY IDENTIFICATIONProduct name : 2,2,2-Trifluoroethyl acrylateProduct Number : 297720AldrichBrand :Sigma-AldrichCompany :3050 Spruce StreetSAINT LOUIS MO 63103USA+18003255832Telephone :+18003255052Fax :Emergency Phone # : (314) 776-65552. HAZARDS IDENTIFICATIONEmergency OverviewOSHA HazardsFlammable liquidGHS Label elements, including precautionary statementsPictogramSignal word DangerHazard statement(s)H225 Highly flammable liquid and vapour.H302 + H312 Harmful if swallowed or in contact with skin.H315 Causes skin irritation.H319 Causes serious eye irritation.H332 Harmful if inhaled.H335 May cause respiratory irritation.Precautionary statement(s)P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.P261 Avoid breathing dust/fume/gas/mist/vapours/spray.P280 Wear protective gloves/protective clothing.P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing.HMIS ClassificationHealth hazard:0Flammability:3Physical hazards:0NFPA RatingHealth hazard:0Fire:3Reactivity Hazard:0Potential Health EffectsInhalation May be harmful if inhaled. May cause respiratory tract irritation.Skin May be harmful if absorbed through skin. May cause skin irritation.Eyes May cause eye irritation.Ingestion May be harmful if swallowed.3. COMPOSITION/INFORMATION ON INGREDIENTSC5H5F3O2Formula :Molecular Weight : 154.09 g/molCAS-No. EC-No.Index-No. Concentration2,2,2-Trifluoroethyl acrylate407-47-6 206-987-6 - -4. FIRST AID MEASURESGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.If inhaledIf breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedDo NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.5. FIRE-FIGHTING MEASURESSuitable extinguishing mediaFor small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.Special protective equipment for fire-fightersWear self contained breathing apparatus for fire fighting if necessary.Further informationUse water spray to cool unopened containers.6. ACCIDENTAL RELEASE MEASURESPersonal precautionsUse personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove allsources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosiveconcentrations. Vapours can accumulate in low areas.Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains.Methods and materials for containment and cleaning upContain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).7. HANDLING AND STORAGEPrecautions for safe handlingAvoid contact with skin and eyes. Avoid inhalation of vapour or mist.Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.Conditions for safe storageKeep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.Recommended storage temperature: 2 - 8 °C8. EXPOSURE CONTROLS/PERSONAL PROTECTIONContains no substances with occupational exposure limit values.Personal protective equipmentRespiratory protectionWhere risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If therespirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and componentstested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).Hand protectionFor prolonged or repeated contact use protective gloves.Eye protectionFace shield and safety glassesSkin and body protectionChoose body protection according to the amount and concentration of the dangerous substance at the work place.Hygiene measuresHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.9. PHYSICAL AND CHEMICAL PROPERTIESAppearanceForm liquidColour colourlessSafety datapH no data availableMelting point no data availableBoiling point 46 °C (115 °F) at 167 hPa (125 mmHg) - lit.Flash point 12 °C (54 °F) - closed cupIgnition temperature no data availableLower explosion limit no data availableUpper explosion limit no data availableDensity 1.216 g/cm3 at 25 °C (77 °F)Water solubility no data available10. STABILITY AND REACTIVITYChemical stabilityStable under recommended storage conditions.Possibility of hazardous reactionsVapours may form explosive mixture with air.Conditions to avoidHeat, flames and sparks.Materials to avoidStrong oxidizing agents, Strong bases, Strong acidsHazardous decomposition productsHazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen fluoride11. TOXICOLOGICAL INFORMATIONAcute toxicityno data availableSkin corrosion/irritationno data availableSerious eye damage/eye irritationno data availableRespiratory or skin sensitizationno data availableGerm cell mutagenicityno data availableCarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as acarcinogen or potential carcinogen by ACGIH.NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as acarcinogen or potential carcinogen by OSHA.Reproductive toxicityno data availableSpecific target organ toxicity - single exposure (GHS)Inhalation - May cause respiratory irritation.Specific target organ toxicity - repeated exposure (GHS)no data availableAspiration hazardno data availablePotential health effectsInhalation May be harmful if inhaled. May cause respiratory tract irritation.Ingestion May be harmful if swallowed.Skin May be harmful if absorbed through skin. May cause skin irritation.Eyes May cause eye irritation.Signs and Symptoms of ExposureTo the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.Additional Information12. ECOLOGICAL INFORMATIONToxicityno data availablePersistence and degradabilityno data availableBioaccumulative potentialno data availableMobility in soilno data availablePBT and vPvB assessmentno data availableOther adverse effectsno data available13. DISPOSAL CONSIDERATIONSProductBurn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material.Contaminated packagingDispose of as unused product.14. TRANSPORT INFORMATIONDOT (US)UN-Number:3272 Class: 3 Packing group: IIProper shipping name: Esters, n.o.s.Marine pollutant: NoPoison Inhalation Hazard: NoIMDGUN-Number: 3272 Class: 3 Packing group: II EMS-No: F-E, S-DProper shipping name: ESTERS, N.O.S. (2,2,2-Trifluoroethyl acrylate)Marine pollutant: NoIATAUN-Number:3272 Class: 3 Packing group: IIProper shipping name: Esters, n.o.s. (2,2,2-Trifluoroethyl acrylate)15. REGULATORY INFORMATIONOSHA HazardsFlammable liquidDSL StatusThis product contains the following components listed on the Canadian NDSL list. All other components are on the Canadian DSL list.2,2,2-Trifluoroethyl acrylate CAS-No. 407-47-6SARA 302 ComponentsSARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.SARA 313 ComponentsSARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.SARA 311/312HazardsFire HazardMassachusetts Right To Know ComponentsNo components are subject to the Massachusetts Right to Know Act.Pennsylvania Right To Know Components2,2,2-Trifluoroethyl acrylate CAS-No.407-47-6Revision DateNew Jersey Right To Know Components2,2,2-Trifluoroethyl acrylate CAS-No.407-47-6Revision DateCalifornia Prop. 65 ComponentsThis product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.16. OTHER INFORMATIONFurther informationCopyright 2010 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only.The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Co., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.。
