《分析化学》上册
一、常用仪器
玻璃漏斗 Glass funnel long stem
试管 test tube test tube brush test tube holder test tube rack
蒸发皿 evaporating dish small
烧杯 beaker
锥形瓶 Erlenmeyer
量筒 grad cylinder
洗瓶 plastic wash bottle
勺皿 casserole ,small
stoppered flask
分液漏斗 separalory funnel
water bath/oil bath
strring bar
magnetic stirrer
冷凝器 condenser
Ballast bottle
圆颈烧瓶 Round-buttom flask
试剂瓶 reagent bottles
托盘天平 platform balance 台秤
0.1g 托盘pan 指针刻度表pointer and scale
crossbeams and sliding weights 游码
分析天平 two-pan/single-pan analytical balance
滴定管 burette glass bead(basic) nozzle
移液管 pipette 胖肚 elongated glass bulb
洗耳球 rubber suction bulb
玻棒 glass rod
玻璃活塞 stopcock
容量瓶 pyknowmeter flasks
比重瓶 (one-mark)volumetric flasks
胖肚吸管 one-mark pipette
刻度吸管 graduated pipettes
实验仪器清单
1、 柜子中 四、抽屉中:
锥形瓶(conical flask) 250ml×4 药匙(medicine spoon)×1
(Erlenmeyer flask) 100 ml×3 滴管(drip tube;dropper)×2
烧杯(beaker) 500 ml×1 玻棒(Glass stic)×2
250 ml×3 木试管夹(test tube clamp;test tube holder)×1
100 ml×3 胖肚吸管(straws) 25 ml×1
50 ml×2 10 ml×1
容量瓶(volumetric flask) 100 ml×2 乳钵(morta)×1
50 ml×4 洗耳球(ear wadhing bulb)
碘量瓶 (iodin numoe flask;iodineflask) 500 ml×3
试剂瓶 (reagent bottle) (无色)×2
(棕色)×2 配洗液:
量筒(cylinder) 100 ml×1 K2Cr2O72g+5ml水→65mlH2SO4
(graduated cylinder)10ml×1 边加边搅拌(stir)。
二、台面上仪器: 一般仪器的洗涤(wash)
铁支架(siderocradle)+蝴蝶架
白瓷板(White Porcelain Board ) (一)清点仪器(to count;to make an inventory)
酸式滴定管(Acid burette) 25 ml×1 配洗液 (Lotion)
碱式滴定管(Alkali burette)25 ml×1 一般仪器的洗涤
三、公用柜中: (二)滴定管(buret;burette)
直型冷凝器(rectocondensor)×1 容量瓶(volumetric flask)
漏斗架 (funnel stand) ×2 移液管(pipe)
水浴锅(water bath kettle) ×1
温度计(Thermometer;hygrometer;hydroscope) ×1
电炉(electric furnace;electric hot plate;electric stove) 四人一个
《分析化学》上册
第一章 绪论
分析化学:analytical chemistry
定性分析:qualitative analysis
定量分析:quantitative analysis
物理分析:physical analysis
物理化学分析:physico-chemical analysis
仪器分析法:instrumental analysis
流动注射分析法:flow injection analysis;FIA
顺序注射分析法:sequentical injection analysis;SIA
化学计量学:chemometrics
第二章 误差的分析数据处理
绝对误差:absolute error
相对误差:relative error
系统误差:systematic error
可定误差:determinate error
随机误差:accidental error
不可定误差:indeterminate error
准确度:accuracy
精确度:precision
偏
差:debiation,d
平均偏差:average debiation
相对平均偏差:relative average debiation
标准偏差(标准差):standerd deviation;S
相对平均偏差:relatibe standard deviation;RSD
变异系数:coefficient of variation
误差传递:propagation of error
有效数字:significant figure
置信水平:confidence level
显著性水平:level of significance
合并标准偏差(组合标准差):pooled standard debiation
舍弃商:rejection quotient ;Q
化学定量分析
第三章 滴定分析概论
滴定分析法:titrametric analysis
滴定:titration
容量分析法:volumetric analysis
化学计量点:stoichiometric point
等当点:equivalent point
电荷平衡:charge balance
电荷平衡式:charge balance equation
质量平衡:mass balance
物料平衡:material balance
质量平衡式:mass balance equation
第四章 酸碱滴定法
酸碱滴定法:acid-base titrations
质子自递反应:autoprotolysis reaction
质子自递常数:autoprotolysis constant
质子条件式:proton balance equation
酸碱指示剂:acid-base indicator
指示剂常数:indicator constant
变色范围:colour change interval
混合指示剂:mixed indicator
双指示剂滴定法:double indicator titration
第五章 非水滴定法
非水滴定法:nonaqueous titrations
质子溶剂:protonic solvent
酸性溶剂:acid solvent
碱性溶剂:basic solvent
两性溶剂:amphototeric solvent
无质子溶剂:aprotic solvent
均化效应:differentiating effect
区分性溶剂:differentiating solvent
离子化:ionization
离解:dissociation
结晶紫:crystal violet
萘酚苯甲醇: α-naphthalphenol benzyl alcohol
奎哪啶红:quinadinered
百里酚蓝:thymol blue
偶氮紫:azo violet
溴酚蓝:bromophenol blue
第六章 配位滴定法
配位滴定法:compleximetry
乙二胺四乙酸:ethylenediamine tetraacetic acid,EDTA
螯合物:chelate compound
金属指示剂:metal lochrome indcator
第七章 氧化还原滴定法
氧化还原滴定法:oxidation-reduction titration
碘量法:iodimetry
溴量法:bromimetry ]
溴量法:bromine method
铈量法:cerimetry
高锰酸钾法:potassium permanganate method
条件电位:conditional potential
溴酸钾法:potassium bromate method
硫酸铈法:cerium sulphate method
偏高碘酸:metaperiodic acid
高碘酸盐:periodate
亚硝酸钠法:sodium nitrite method
重氮化反应:diazotization reaction
重氮化滴定法:diazotization titration
亚硝基化反应:nitrozation reaction
亚硝基化滴定法:nitrozation titration
外指示剂:external indicator
外指示剂:outside indicator
重铬酸钾法:potassium dichromate method
第八章 沉淀滴定法
沉淀滴定法:precipitation titration
容量滴定法:volumetric precipitation method
银量法:argentometric method
第九章 重量分析法
重量分析
法:gravimetric analysis
挥发法:volatilization method
引湿水(湿存水):water of hydroscopicity
包埋(藏)水:occluded water
吸入水:water of imbibition
结晶水:water of crystallization
组成水:water of composition
液-液萃取法:liquid-liquid extration
溶剂萃取法:solvent extration
反萃取:counter extraction
分配系数:partition coefficient
分配比:distribution ratio
离子对(离子缔合物):ion pair
沉淀形式:precipitation forms
称量形式:weighing forms
《分析化学》下册
仪器分析 概述
物理分析:physical analysis
物理化学分析:physicochemical analysis
仪器分析:instrumental analysis
第十章 电位法滴定法
电化学分析:electrochemical analysis
电解法:electrolytic analysis method
电重量法:electtogravimetry
库仑法:coulometry
库仑滴定法:coulometric titration
电导法:conductometry
电导分析法:conductometric analysis
电导滴定法:conductometric titration
电位法:potentiometry
直接电位法:dirext potentiometry
电位滴定法:potentiometric titration
伏安法:voltammetry
极谱法:polarography
溶出法:stripping method
电流滴定法:amperometric titration
化学双电层:chemical double layer
相界电位:phase boundary potential
金属电极电位:electrode potential
化学电池:chemical cell
液接界面:liquid junction boundary
原电池:galvanic cell
电解池:electrolytic cell
负极:cathrode
正极:anode
电池电动势:eletromotive force
指示电极:indicator electrode
参比电极:reference electroade
标准氢电极:standard hydrogen electrode
一级参比电极:primary reference electrode
饱和甘汞电极:standard calomel electrode
银-氯化银电极:silver silver-chloride electrode
液接界面:liquid junction boundary
不对称电位:asymmetry potential
表观PH值:apparent PH
复合PH电极:combination PH electrode
离子选择电极:ion selective electrode
敏感器:sensor
晶体电极:crystalline electrodes
均相膜电极:homogeneous membrance electrodes
非均相膜电极:heterog eneous membrance electrodes
非晶体电极:non- crystalline electrodes
刚性基质电极:rigid matrix electrode
流流体载动电极:electrode with a mobile carrier
气敏电极:gas sensing electrodes
酶电极:enzyme electrodes
金属氧化物半导体场效应晶体管:MOSFET
离子选择场效应管:ISFET
总离子强度调节缓冲剂:total ion strength adjustment buffer,TISAB
永停滴定法:dead-stop titration
双电流滴定法(双安培滴定法):double amperometric titration
第十一章 光谱分析法概论
普朗克常数:Plank constant
电磁波谱:electromagnetic spectrum
光谱:spectrum
光谱分析法:spectroscopic analysis
原子发射光谱法:atomic emission spectroscopy
质量谱:mass spectrum
质
谱法:mass spectroscopy,MS
第十二章 紫外-可见分光光度法
紫外-可见分光光度法:ultraviolet and visible spectrophotometry;UV-vis
肩峰:shoulder peak
末端吸收:end absorbtion
生色团:chromophore
助色团:auxochrome
红移:red shift
长移:bathochromic shift
短移:hypsochromic shift
蓝(紫)移:blue shift
增色效应(浓色效应):hyperchromic effect
减色效应(淡色效应):hypochromic effect
强带:strong band
弱带:weak band
吸收带:absorption band
透光率:transmitance,T
吸光度:absorbance
谱带宽度:band width
杂散光:stray light
噪声:noise
暗噪声:dark noise
散粒噪声:signal shot noise
闪耀光栅:blazed grating
全息光栅:holographic graaing
光二极管阵列检测器:photodiode array detector
偏最小二乘法:partial least squares method ,PLS
褶合光谱法:convolution spectrometry
褶合变换:convolution transform,CT
离散小波变换:wavelet transform,WT
多尺度细化分析:multiscale analysis
供电子取代基:electron donating group
吸电子取代基:electron with-drawing group
第十三章 荧光分析法
荧光:fluorescence
荧光分析法:fluorometry
X-射线荧光分析法:X-ray fulorometry
原子荧光分析法:atomic fluorometry
分子荧光分析法:molecular fluorometry
振动弛豫:vibrational relexation
内转换:internal conversion
外转换:external conversion
体系间跨越:intersystem crossing
激发光谱:excitation spectrum
荧光光谱:fluorescence spectrum
斯托克斯位移:Stokes shift
荧光寿命:fluorescence life time
荧光效率:fluorescence efficiency
荧光量子产率:fluorescence quantum yield
荧光熄灭法:fluorescence quemching method
散射光:scattering light
瑞利光:Reyleith scanttering light
拉曼光:Raman scattering light
第十四章 红外分光光度法
红外线:infrared ray,IR
中红外吸收光谱:mid-infrared absorption spectrum,Mid-IR
远红外光谱:Far-IR
微波谱:microwave spectrum,MV
红外吸收光谱法:infrared spectroscopy
红外分光光度法:infrared spectrophotometry
振动形式:mode of vibration
伸缩振动:stretching vibration
对称伸缩振动:symmetrical stretching vibration
不对称伸缩振动:asymmetrical stretching vibration
弯曲振动:bending vibration
变形振动:formation vibration
面内弯曲振动:in-plane bending vibration,β
剪式振动:scissoring vibration,δ
面内摇摆振动:rocking vibration,ρ
面外弯曲振动:out-of-plane bending vibration,γ
面外摇摆振动:wagging vibration,ω
蜷曲振动:twisting vibration ,τ
对称变形振动:symmetrical deformation vibration ,δs
不对称变形振动:asymmetrical deformation vibration, δas
特征吸收峰:charateristic avsorption band
特征频率:characteristic frequency
相关吸收峰:correlation a
bsorption band
杂化影响:hybridization affect
环大小效应:ring size effect
吸收峰的强度:intensity of absorption band
环折叠振动:ring prckering vibration
第十五章 原子吸收分光光度法
原子光谱法:atomic spectroscopy
原子吸收分光光度法:atomic absorption spectrophotometry,AAS
原子发射分光光度法:atomic emmsion spectrophotometry,AES
原子荧光分光光度法:atomic fluorescence spectrophotometry,AFS
第十六章 核磁共振波谱法
核磁共振:nuclear magnetic resonance,NMR
核磁共振波谱:NMR spectrum
核磁共振波谱法:NMR spectroscopy
扫场:swept field
扫频:seept frequency
连续波核磁共振:continuous wave NMR,CW NMR
Fourier变换NMR:PFT-NMR,FT-NMR
二维核磁共振谱:2D-NMR
质子核磁共振谱:proton magnetic resonance spectrum,PMR
氢谱:1H-NMR
碳-13核磁共振谱:13C-NMR spectrum,13CNMR
自旋角动量:spin angular momentum
磁旋比:magnetogyric ratio
磁量子数:magnetic quantum number,m
进动:precession
弛豫历程:relaxation mechanism
局部抗磁屏蔽:local diamagnetic shielding
屏蔽常数:shielding constant
化学位移:chemical shift
国际纯粹与应用化学协会:IUPAC
磁各向异性:magnetic anisotropy
远程屏蔽效应:long range shielding effect
结面:nodal plane
自旋-自旋偶合:spin-spin coupling
自旋-自旋分裂:spin=spin splitting
单峰:singlet,s
双峰:doublet,d
三重峰:triplet,t
四重峰:quartet
五重峰:quintet
六重峰:sextet
偕偶:geminal coupling
邻偶:vicinal coupling
远程偶合:long range coupling
磁等价:magnetic eqivalence
自旋系统:spin system
一级光谱:first order spectrum
二级光谱(二级图谱):second order spectrum
C-H光谱:C-H correlated spectroscopy,C-H COSY
第十七章 质谱法
质谱分析法:mass spectrometry
质谱:mass spectrum,MS
棒图:bar graph
选择离子检测:selected ion monitoring ,SIM
直接进样:direct probe inlet ,DPI
接口:interface
气相色谱-质谱联用:gas chromatography-mass spectrometry,GC-MS
高效液相色谱-质谱联用:high performance liquid chromatography-mass spectrometry,HPLC-MS
电子轰击离子源:electron impact source,EI
离子峰:quasi-molecular ions
化学离子源:chemical ionization source,CI
场电离:field ionization,FI
场解析:field desorptiion,FD
快速原子轰击离子源:fast stom bombardment ,FAB
质量分析器:mass analyzer
磁质谱仪:magnetic-sector mass spectrometer
四极杆质谱仪(四极质谱仪):quadrupole mass spectrometer
原子质量单位:amu
离子丰度:ion abundance
相对丰度(相对强度):relative avundance
基峰:base peak
质量范围:mass range
分辨率:resolution
灵敏度:sensitivity
信噪比:S/N
分子离子:molecular ion
碎片离子:fragment ion
同位素离子:isoto
pic ion
亚稳离子:metastable ion
亚稳峰:metastable peak
母离子:paren ion
子离子:daughter
含奇数个电子的离子:odd electron
含偶数个电子的离子:even eletron,EE
均裂:homolytic cleavage
异裂(非均裂):heterolytic cleavage
半均裂:hemi-homolysis cleavage
重排:rearragement
分子量:MW
α-裂解:α-cleavage
第十八章 色谱分析法概论
色谱法(层析法):chromatography
固定相:stationary phase
流动相:mobile phase
超临界流体色谱法:SFC
高效毛细管电泳法:high performance capillary electroporesis,HPEC
气相色谱法:gas chromatography,GC
液相色谱法:liquid cromatography,LC
超临界流体色谱法:supercritical fluid chromatography,SFC
气-固色谱法:GSC
气-液色谱法:GLC
液-固色谱法:LSC
液-液色谱法:LLC
柱色谱法:column chromatography
填充柱:packed column
毛细管柱:capillary column
微填充柱:icrobore packed column
高效液相色谱法:high performance liquid chromatography,HPLC
平板色谱法:planar
平板色谱法:plane chromatography
纸色谱法:paper chromatography
薄层色谱法:thin layer chromatography,TLC
薄膜色谱法;thiin film chomatography
毛细管电泳法:capillary electrophoresis,CE
分配色谱法:partition chromatography
吸附色谱法:adsorpion chromaography
离子交换色谱法:ion exchange chromatography,IEC
空间排阻色谱法:steric exclusion chromatography,SEC
亲和色谱法:affinity chromatography
分配系数:distribution cofficient
狭义分配系数:partition coefficient
凝胶色谱法:gel chromatography
凝胶渗透色谱法:gel permeation chromatography,GPC
凝胶过滤色谱法:gel filtration chromatography,GFC
渗透系数:permeation coefficien;Kp
化学键合相色谱法:chemically bonded-phase chromatography
分配系数:distribution coefficient
靛菁绿:indocyanine
气相色谱-傅立叶变换红外光谱:GC-FTIR
第十九章 经典液相色谱法
薄层色谱法:TLC
吸附:adsorption
活化:activation
脱活性:deactivation
交联度:degree of cross linking
交换容量:exchange capacity
薄层板:thin layer plate
展开剂:developing solvent ,developer
临界胶束浓度:criticak micolle concentration ,CMC
相对比移值:relative Rf, Rr
分离度:resolution ,R
分离数:separation number,SN
煅石膏:Gypsum
羧甲基纤维素钠:CMC-Na
吸收光谱联用:TLC-UV
薄层色谱-荧光联用:TLC-F
薄层色谱-红外吸收光谱联用:TLC-IR
薄层色谱法:TLC-MS
纸色谱法:paper chromatography
上行展开:ascending development
下行法展开:descending development
双向展开:two dimensional develoooment
第二十章 气相色谱法
气相色谱法:gas chromatography
前延峰:leading peak
拖尾峰:tailing peak
对称因子:symmetry factor,fs
保留时间:rete
ntion time
保留体积:retention volume
死时间:dead time
调整保留时间:asjusted retention time
半峰宽:peak width at half height,W1/2 or Y1/2
峰宽:peak width,W
等温线:isotherm
理论塔板高度:height equivalent to atheoretical plate
化学键合相:chemically bonded phase
丁二酸二乙二醇聚酯:polydiethylene glycol succinate,PDEGS,DEGS
高分子多孔微球:GDX
苯乙烯:STY
乙基乙烯苯:EST
二乙烯苯:DVB
涂壁毛细管柱:wall coated open tubular column,WCOT
载体涂层毛细管柱:supprot coated open tubular column,SCOT
热导检测器:thermal conductivity detector,TCD
氢焰离子化检测器:hydrogen flame ionization detector,FID
电子捕获检测器:electron capture detector ,ECD
噪声:noise,N
漂移:drift,d
灵敏度:sensitivity
检测限(敏感度):detectability,D,M
分离度:resolution
归一化法:normalization method
外标法:external standardization
第二十一章 高效液相色谱法
高效液相色谱法:high performance liquid chromatography,HPLC
高速液相色谱法:high speed LC,HSLC
高压液相色谱法:high pressure LC,HPLC
高分辨液相色谱法:high resolution LC,HRLC
液固吸附色谱法(液固色谱法):liquid-solid adsorption chromatography,LSC
液液色谱法:liquid-liquid chromatography,LLC
正相:normal phase,NP
反相:reversed phase,RP
化学键合相色谱法:bonded phase chromatography,BPC
十八烷基:octadecylselyl,ODS
离子对色谱法:paired ion chromatography,PIC
反相离子对色谱法:RPIC
离子抑制色谱法:ion suppression chromatography,ISC
离子色谱法:ion chromatography,IC
手性色谱法:chiral chromatography,CC
环糊精色谱法:cyclodextrin chromatography,CDC
胶束色谱法:micellar chromatography,MC
亲和色谱法:affinity chromatography,AC
固定相:stationary phase
化学键合相:chemically bonde phase
封尾、封顶、遮盖:end capping
手性固定相:chiral stationary phase,CSP
恒组成溶剂洗脱:isocraic elution
梯度洗脱:gradient elution
紫外检测器:ultraviolet detector,UVD
荧光检测器:fluorophotomeric detector,FD
电化学检测器:ECD
示差折光检测器:RID
光电二极管检测器:photodiode array detector ,DAD
三维光谱-波谱图:3D-spectrochromatogram
蒸发光散射检测器:evaporative light scattering detector,ELSD
安培检测器:ampere detector,AD
高效毛细管电泳法:high performance capillary electrophoresis,HPCE
淌度:mobility
电泳:electrophoresis
电渗:electroosmosis
动力进样:hydrodynamic injection
电动进样:electrokinetic injection
毛细管区带电泳法:capillary zone electrophoresis,CZE
胶束电动毛细管色谱:micellar electrokinetic capillary chromatography,MECC
毛细管凝胶电泳:capillary gel electrophoresis,CGE
筛分:sieving
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