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BMS
Borane-methyl sulfide
Bn
Benzyl
BOC
t-Butylcarbonyl
BOM
Benzyloxymethyl
BOP
Benzotriazol-1-yloxytris(dimethylamino) phosphonium hexafluorophosphate
BOP-Cl
N,N-Bis(2-oxo-3-oxazolidinyl)phosphinic
Ar
Aryl芳香基
ATP
Adenosine 5’-triphosphate三磷酸腺苷
ATPase
Adenosinetriphosphatase ATP酶
Azb
p-Azidobenzyl
Bam
Benzamidomethyl
BBA
Butane-2,3-bisacetal
BBn
p-Bromobenzyl
9-BBN
E2
Bimolecular elimination
ED50
Dose that is effective in 50% of test subjects
EDC
1-Ethyl-3-(3’-dimethylaminopropyl)carbodiimide
EDTA
Ethylenediaminetetraacetic acid
FD Field
Field distortion (in MS)
FG
Founctional group
FID
Flame ionization detection or Free induced decay (in NMR)
Fm
9-Fluorenylmethyl
FMOC
9-Fluorenylmethylcarbamate
DMSO
Dimethyl sulfoxide or methyl sulfoxide
DMT
Dimethoxytrityl
DMTr
Di(p-methoxyphenyl)phenylmethyl
DNA
Deoxyribonucleic acid
DNB
p,p’-Dinitrobenzhyrryl
DNMBS
4-(4’,8’-Dimethoxynaphthylmethyl)benzenesulfonyl
Dmoc
Dithianylmethoxycarbonyl
DMP
Dimethylpropane
Dmp
Dimethylphosphinyl
DMPM
3,4-Dimethoxybenzyl
DMPU
1,3-Dimethyl-3,4,5,6-tetrhydro-2(1H)-pyrimidinone
DMS
Dimethyl sulLeabharlann Baiduate
Adoc
1-Adamantyloxycarbonyl
Adpoc
1-(1-Adamantyl)-1-methylethoxycarbonyl
AIBN
2,2’-Azobis(2-methylpropionitrile) or Azobisisobutyronitrile
All
Allyl
Alloc
Alloxycarbonyl
DG
Diacyl glycerol
DIAD
Diisopropyl azodicarboxylate
DIBAH DIBAL
Diisobutylalumium hydride
Dim
2-(1,3-Dithianyl)methyl
DIPEA
Diisopropylethylamine
DIPT
Diisopropyl tartrate
LDA
Lithium diisopropylamide
Als
Allylsulfonyl
AMB
2-(Acetoxymethyl)benzoyl
AN
4-Methoxyphenyl or anisyl
Anpe
2-(4-Acetyl-2-nitrophenyl)ethyl
AOC
Allyloxycarbonyl
p-AOM
p-Anisyloxymrthyl or (4-methoxyphenoxy)methyl
ABO
2,7,8-Trioxabicyclo[3.2.1]octyl
Ac
Acetyl
ACBZ
4-Azidobenzyloxycarbonyl
ACE
α-Chloroethoxycarbonyl
AcHmb
2-Acetoxy-4-methoxybenzyl
Acm
Acetamidomethyl
Ad
1-Adamantyl
DBN
1,5-Diazabicyclo[4.3.0]non-5ene
DBU
1,8-Diazabicyclo[5.4.0]undec-7-ene
DCC
Dicyclohexylcarbodiimide
DCU
二环己基脲1,3-dicyclohexylurea;n,n'-dicyclohexyl-ure;n,n'-dicyclohexylurea
HPLC
High performance liquid chromatography
HRMS
High-resolution mass spectrum
hν
Irradiation with light
Hz
Hertz
hZ
Homobenzyloxycarbonyl
ICR
Ion cyclotron resonance
Bu
Butyl
s-BU
Sec-Butyl
t-Bu
tert-Butyl
Bum
t-Butoxymethyl
t-Bumeoc
1-(3,5-Di-t-butylphenyl)-1-methylethoxycarbonyl
Bz
Benzoyl
Cam
Carboxyamidomethyl
cAMP
Adenosine cyclic 3’,5’-phosphate
COD
1,5-Cyclooctadiene
COSY
Correlation spectroscopy
COT
Cyclooctatetrene
Cp
Cyclopentadienyl
CPTr
4,4’,4”-Tris(4,5-dichlorophthalimido)riphenylmethyl
CSA
Camphorsulfonic acid
KHMDS
Potassium bis(trimethylsilyl)amide or potassium hexamrthyldisilane
L
Triphenylphosphine ligand or liter
LAH
Lithium aluminum hydride
LCAO
Linear combination of atomic orbitals
DCMME
Dichloromethylammonium chloride
DDQ
2,3-Dichloro-5,6-dicyano-1,4-benzoquinone
DEAD
Diethylazodicarboxylate
DEIPS
Diethylisopropylsilyl
DEPT
Distortionless enhancement by polarization transfer
EE
1-Ethoxyethyl
ee
Enantiomeric excess
EI
Electron impact (in MS)
ESR
Electron spin resonance
Et
Ethyl
FAB
Fast atom bombardment (in MS)
Fcm-NR2
N-Ferrocenylmethyl
9-Borabicyclo[3.3.1]nonane
BDMS
Biphenyldimethylsilyl
BDT
1,3-Benzodithiolan-2-yl
Bic
5-Benzisoxazolymethoxycarbonyl
Bmpc
2,4-Dimethylthiophenoxycarbonyl
Bmpm
1,1-Bis(4-methoxyphenyl)-1’-pyrenylmethyl
CAN
Cerium(IV) ammonium nitrate
Cbz
Benzyloxycarbonyl
CD
Circular dichrosim
CDI
1,1’-Carbonyldiimidazole
Cee
1-(2-Chloroethoxy)ethyl
CI
Chemical ionization (in MS) Configuration interaction (in MO theory)
DNP
2,4-Dinitrophenyl
Dobz
p-(Dihydroxyboryl)benzyloxycarbonyl
DPM
Diphenylmethyl
DPMS
Diphenylmethylsilyl
Dpp
Diphenylphosphinyl
DPPA
Diphenylphosphoryl azide
Dppe
DAST
Diethylaminosulfurtrifluoride
DB-t-BOC
1,1-Dmethyl-2,2-dibromoethoxycarbonyl
DBD-Tmoc
2,7-Di-t-butyl[9-(10,10-dioxo-10,10,10,10-tetrahydrothioxanthyl)methy lcarbonyl
2-(Diphenylphosphino)ethyl
Dppm
(Diphenyl-4-pyridyl)methyl
Dpt
Diphenylthiophosphinyl
DTBMS
Di-t-butylsilylene
Dts
Dithiasuccinimidyl
E1
Unimolecular elimination
DMAC
Dimethylacetamide
DMAD
Diethyl acetylenedicarboxylate
DMAP
4-Dimethylaminopyridine
DME
Dimethoxyethane
DMF
N,N-Dimethylformamide
DMIPS
Dimethylisopropylsilyl
IDTr
3-(Imidazole-1-ylmethyl)-4’,4”-dimethoxytriphenylmethyl
Im
Imidazole-1-yl or 1-imidazolyl
iMds
2,6—Dimethoxy-4-methylbenzenesulfonyl
INDO
Incomplete neglect of differential overlap
CTMP
1-[(2-Chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl
Cys
Cysteine
δ
Chemical shift in ppm
d
Day
DABCO
1,4-Diazabicyclo[2.2.2]octane
DAM
Di(4-methoxyphenyl)methyl
IP
Ionization potential
Ipaoc
1-Isopropylallyloxycarbonyl
IPDMS
Isopr
opyldimethylsilyl
IR
Infrared
J
Coupling constant (in NMR)
k
Kilo
KAPA
Potassium 3-aminopropylamide
CIDNP
Chemically induced dynamic nuclear polarization
cm
Centmeter
CMPI
2-Chloro-1-methylpyridium chloride
CNDO
Complete neglect of differential overlap
Coc
Cinnamyloxycarbonyl
bp
Boiling point
Bpoc
1-methyl-1-(4-biphenyl)ethoxycarbonyl
Bpy
2,2’-Bipyridyl
BSA
Bistrimethylsilyl acetamide
Bt
Benzotriazo-1-yl or 1-benzotriazolyl
BTBA
Benzyltributylammonium chloride
Fp
η5
FT
Foutier transform
g
Gram
GC
Gas chromatography
GTP
Guanosine 5’-triphosphate
GUM
Guaiacolmethyl
h
Hour
HCA
Hexachloroacetone
Hex
Hexyl
HMDS
1,11,3,3,3-Hexamethyldisilazane
HMO
Huckel molecular orbital
HMPA
Hexamethylphosphoramide
HMPT
Hexamethylphosphoroustriamide
HOBT
1-Hydroxybenzotriazole
HOMO
Highest occupied molecular orbital